Silver_Is_Money
Larry Sayre, Developer of 'Mash Made Easy'
This peer reviewed study (which claims to be in agreement with other documented studies) offers yet more reason as to why the math modeling of mash pH will never be a precise science:
https://onlinelibrary.wiley.com/doi/pdf/10.1002/j.2050-0416.1975.tb03668.x
If you want to lower your pH, mash via single infusion. If you want to "significantly" raise your pH, follow a step mash profile.
In agreement with the findings of Burger et-al* it was found that the lager malts gave worts of significantly higher pH when mashed using the temperature-programmed system as opposed to the single temperature infusion system. Clearly the major effect of malt on the pH of worts is modified by the system of mashing employed.
https://onlinelibrary.wiley.com/doi/pdf/10.1002/j.2050-0416.1975.tb03668.x
If you want to lower your pH, mash via single infusion. If you want to "significantly" raise your pH, follow a step mash profile.