If you have a large enough pot to hold the full volume of water plus the grain the process it the same. The bag of wet grains will weigh twice as much so take that into account as it can be hard to hold while draining. You also may not boil off twice as much so be prepared to boil longer if necessary. Twice the volume of wort also means it has twice the energy (heat) to remove while chilling so having a wort chiller would be nice. Chilling in the sink will take a long time but if you don't have a chiller you can get pretty good results by putting the pot of hot wort into a tub that is deep enough to hold water to about the level of the wort in the pot and making is so you can overflow it to maintain this level as you add cold water. I like to brew in the winter and use snow to add to the tub because I know that as long as I keep snow mixed with the water it will be chilling fast.