If I understand your question correctly, you are basically asking if doubling the extract will double the final gravity. Is that what you are asking?
In general, yeah, that's the result, but there are some limitations. For example, most yeast has an upper limit to what ABV it can take before it starts to slow down. If your recipe is going to give you 7% ABV when it's done, doubling the sugars would be something like 14%, but chances are your yeast isn't going to want to ferment that far. That beer would probably end up being around 9% or so, and being really sweet, but it would depend on the yeast and fermentation conditions, really.
But, yeah, if you had a recipe that would get you around 3% and you doubled the extract, it would end up being around 6%, assuming your fermentation happened correctly.
The amount of yeast you should use doesn't work like that, though. Doubling the sugar doesn't necessarily mean doubling the yeast.
There are a lot of good websites out there that allow you to enter your ingredients, and your water volume, and your yeast, and it will spit out what ABV you can expect, if you wanted to try and hit a certain ABV. There are also websites that can tell you how much yeast to use, too.