Actually it doesn't (with one caveat) and here's why. A lot of people think it is the junction of the dissimilar metals that is the basis for the voltage the thermocouple develops but it isn't. It is that if one end of a wire is at one temperature and the other at another there will be a difference in electrical potential between the two ends (Seebeck effect). Now if one wire is chromel and the other is alumel (Type K thermocouple) the voltages between the proximal and distal ends will, for the same temperature difference, be different. If the wires are joined at one end clearly there will be a voltage difference between the two unjoined ends and that difference will depend on the wire types, the temperature at the joint and the temperature at the terminal end (the temperature difference from one end to the other). A millivolt meter placed between those two ends will measure that voltage difference. Now if we connect each of those wire ends to, say, a copper wire of some length (actually it doesn't matter how long, within reason) and connect those to the millivolt meter it will read the voltage at the ends of the thermocouple wire even if the meter and the junction point with the thermocouple wire are at different temperatures because the Seebeck voltages in the copper wires cancel each other. Now if the meter and junction point are not at the same temperature the meter is going to interpret the voltage reading as if the ends of the alumel and chromel wires were at the temperature at the meter connection point, not the the temperature where the joint with copper wire is made. So the caveat I mentioned above is that the temperature of the place where the joint with copper is made must be the same as the temperature of the meter (where the temperature is measured and used to convert voltage to thermocouple temperature reading). So if your joint is in room air and your meter is in room air you will be fine using copper (or any other pair that are the same) for the extension. If your thermocouple is in the kiln room and the joint is in the kiln room and the meter is in the air conditioned office, that's not so good.Regarding what wire to use for connections, it really does matter, but it's been a long time since I looked at the details.
Actually it doesn't (with one caveat) and here's why. A lot of people think it is the junction of the dissimilar metals that is the basis for the voltage the thermocouple develops but it isn't. It is that if one end of a wire is at one temperature and the other at another there will be a difference in electrical potential between the two ends (Seebeck effect). Now if one wire is chromel and the other is alumel (Type K thermocouple) the voltages between the proximal and distal ends will, for the same temperature difference, be different. If the wires are joined at one end clearly there will be a voltage difference between the two unjoined ends and that difference will depend on the wire types, the temperature at the joint and the temperature at the terminal end (the temperature difference from one end to the other). A millivolt meter placed between those two ends will measure that voltage difference. Now if we connect each of those wire ends to, say, a copper wire of some length (actually it doesn't matter how long, within reason) and connect those to the millivolt meter it will read the voltage at the ends of the thermocouple wire even if the meter and the junction point with the thermocouple wire are at different temperatures because the Seebeck voltages in the copper wires cancel each other. Now if the meter and junction point are not at the same temperature the meter is going to interpret the voltage reading as if the ends of the alumel and chromel wires were at the temperature at the meter connection point, not the the temperature where the joint with copper wire is made. So the caveat I mentioned above is that the temperature of the place where the joint with copper is made must be the same as the temperature of the meter (where the temperature is measured and used to convert voltage to thermocouple temperature reading). So if your joint is in room air and your meter is in room air you will be fine using copper (or any other pair that are the same) for the extension. If your thermocouple is in the kiln room and the joint is in the kiln room and the meter is in the air conditioned office, that's not so good.
To verify what I've said get out the trusty Fluke (or whatever you use), plug in the thermocouple and let the reading stabilize. Now unplug the thermocouple, plug in the normal test leads and use put them on the thermocouple banana plugs. You won't see an appreciable temperature difference (other than from air currents, etc.).
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